Because you are married, you cannot be treated as single. You can file a joint return, or you can opt to file as “married filing separately.” However, if spouses live apart and meet certain tests, one may qualify to file as head of household instead of married filing separately. To do this, you must have a qualifying person live with you (or a dependent parent even if not living with you); a spouse is not a qualifying person.
Advance payment of current tax liability based either on wage withholdings or installment payments of your estimated tax liability. To avoid penalties, you generally must pay to the IRS either 90% of your final tax liability, or either 100% or 110% of the prior year’s tax liability, depending on your adjusted gross income.