No. The value of employer-paid health insurance for an employee, spouse, and dependent is a tax-free fringe benefit. However, under the Affordable Care Act, employers (other than small employers currently exempt from this obligation) must report health insurance on W-2s. Presumably, this information is being used by the government for rules in the future; there is no current or future rule on the books that taxes this fringe benefit.
A husband and wife who are required to live apart from each other by the terms of a decree of separate maintenance. Payments under the decree are deductible by the payor and taxable to the payee as alimony.